کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1443883 1509482 2006 10 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Design and electropolymerization of new chiral thiophene–salen complexes
موضوعات مرتبط
مهندسی و علوم پایه مهندسی مواد بیومتریال
پیش نمایش صفحه اول مقاله
Design and electropolymerization of new chiral thiophene–salen complexes
چکیده انگلیسی

New chiral thiophene-containing salen ligands have been synthesized. The corresponding metal complexes (Co, Cu, Cr and Ni) were prepared and electropolymerized at a platinum electrode by cyclic voltammetry. The resulting polymers exhibited stable and quasi-reversible redox processes when submitted to voltammetric repeated scans, whatever the nature of the metal or the structure of the ligand. Preliminary catalytic tests have been performed to examine the efficiency of these new chiral polymeric complexes as asymmetric heterogeneous catalysts.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Synthetic Metals - Volume 156, Issues 2–4, 1 February 2006, Pages 166–175
نویسندگان
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