کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1443978 1509478 2006 8 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Ru(II) complexes containing dihydro-1,1,3,3-tetramethyl-7,8-diazacyclopenta[1]phenanthren-2-ol ligand: Synthesis and their electrochemiluminescent characteristics
موضوعات مرتبط
مهندسی و علوم پایه مهندسی مواد بیومتریال
پیش نمایش صفحه اول مقاله
Ru(II) complexes containing dihydro-1,1,3,3-tetramethyl-7,8-diazacyclopenta[1]phenanthren-2-ol ligand: Synthesis and their electrochemiluminescent characteristics
چکیده انگلیسی

A series of new ruthenium(II) complexes containing dihydro-1,1,3,3-tetramethyl-7,8-diazacyclopenta[1]phenanthren-2-ol (DTDP-OH) ligand, such as [Ru(DTDP-OH)n(L)3−n]2+ (L = 2,2′-bipyridyl (bpy), o-phenanthroline (o-phen), 2,2′-bipyridine-4,4′-dicarboaldehyde (bpy-(CHO)2), 1,3-dihydro-1,1,3,3-tetramethyl-7,8-diazacyclopenta[1]phenanthren-2-one(DTDP), n = 1, 2, 3) were synthesized and their electrochemical and photophysical properties were studied. The synthesized Ru(II) complexes containing the DTDP-OH ligand showed strong MLCT absorptions at 420–487 nm. All the synthesized Ru(II) complexes containing the DTDP-OH ligand exhibited more intensive ECL emissions than the well-known [Ru(o-phen)3]2+ does. In particular, the ECL intensities of [Ru(DTDP-OH)2(o-phen)]2+ and [Ru(DTDP-OH)2(bpy-(CHO)2)]2+ were observed to be more than 2-fold greater than that of [Ru(o-phen)3]2+.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Synthetic Metals - Volume 156, Issues 11–13, 1 June 2006, Pages 885–892
نویسندگان
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