کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1473577 991050 2015 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Low-toxic gelcasting of giant dielectric-constant CaCu3Ti4O12 ceramics from the molten salt powder
موضوعات مرتبط
مهندسی و علوم پایه مهندسی مواد سرامیک و کامپوزیت
پیش نمایش صفحه اول مقاله
Low-toxic gelcasting of giant dielectric-constant CaCu3Ti4O12 ceramics from the molten salt powder
چکیده انگلیسی


• CCTO nano powder was synthesized by a molten salt method in NaCl flux.
• Aqueous CCTO slurry with high solid loading and low viscosity was obtained.
• A low-toxicity monomer, DMAA was used as the gelling agent.
• CCTO green body with homogeneous microstructure and high strength was obtained.
• CCTO ceramics prepared by gelcasting have giant dielectric constant and low loss.

CaCu3Ti4O12 (CCTO) nano powder was synthesized using a molten salt synthesis method in NaCl flux. Synthesis temperature and holding time were investigated. The suitable synthesis condition is 800 °C for 2 h. Aqueous CCTO slurry with high solid loading and low viscosity was prepared by using acrylic acid-2-acrylamido-2-methypropane sulfonic acid copolymer (AA/AMPS) as the dispersant. AA/AMPS dosage and pH condition have been optimized as AA/AMPS dosage of 3 wt% and pH about 9.08. A low-toxicity and water-soluble monomer, N,N-dimethylacrylamide (DMAA) was used as the gelling agent. CCTO green body fabricated by the gelcasting method has the homogeneous microstructure and relatively high mechanical strength of 9.27 MPa. CCTO ceramics obtained by the gelcasting method have higher dielectric constant than those prepared by the cold isostatic pressing method and show relatively low dielectric loss of below 0.2 in the wide frequency range of 102–105 Hz.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of the European Ceramic Society - Volume 35, Issue 13, November 2015, Pages 3529–3534
نویسندگان
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