کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1475665 991125 2012 7 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Morphological evolution of NiO-ScSZ composite in a high-temperature reducing atmosphere
موضوعات مرتبط
مهندسی و علوم پایه مهندسی مواد سرامیک و کامپوزیت
پیش نمایش صفحه اول مقاله
Morphological evolution of NiO-ScSZ composite in a high-temperature reducing atmosphere
چکیده انگلیسی

The microstructural change in composite of nickel oxide and scandia-stabilized zirconia (NiO-ScSZ) under a reducing atmosphere was observed by scanning electron microscopy (SEM). The morphological transformation was noticeable after high-temperature treatment with the formation of two peculiar microstructures; i.e., fibrous zirconia and metallic nickel with wrinkled surface. It was suggested that partial reduction of the nickel species dissolved in ScSZ lattice triggered the formation of these characteristic morphologies. The growth of fibrous zirconia appeared to be promoted via interfacial reaction between the metallic Ni particles and the zirconia phase. The agglomeration of metallic nickel proceeded by the reduction at high temperatures and then the surface was transformed to the wrinkled morphology. The unique wrinkled pattern was often observed for the large agglomerated nickel particles. This drastic change in Ni-ScSZ microstructure upon the high-temperature reduction degraded the electrochemical performance of solid oxide fuel cells.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of the European Ceramic Society - Volume 32, Issue 1, January 2012, Pages 107–113
نویسندگان
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