کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1476365 991152 2010 16 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Red ceramic pigments of terbium-doped ceria prepared through classical and non-conventional coprecipitation routes
موضوعات مرتبط
مهندسی و علوم پایه مهندسی مواد سرامیک و کامپوزیت
پیش نمایش صفحه اول مقاله
Red ceramic pigments of terbium-doped ceria prepared through classical and non-conventional coprecipitation routes
چکیده انگلیسی

Reddish ceramic pigments based on cerianite compositions Ce1−xTbxO2 (x = 0.1, 0.2 and 0.3) and Ce0.9Tb0.05Y0.05O2 have been prepared. Firstly, the optimal composition giving the best red colour was selected (Ce0.9Tb0.1O2) from ceramic and chlorides coprecipitation samples fired at 1100–1500 °C. Secondly, the effect of using different classical and non-conventional coprecipitation routes on the synthesis and colouring performance of CeO2-Tb red pigments was analyzed for the first time. In addition to classical coprecipitation we tested also the use of hydrothermal treatment and other more homogeneous coprecipitation methods with oxalates and urea. Homogeneous coprecipitation was also combined with ultrasonic or microwave irradiation. Samples were characterized by thermal analysis, XRD, SEM/EDX, optical spectroscopy and colour measurements. Interestingly, the optimization of synthesis methods enabled to obtain more homogeneous (single phase) CeO2-Tb solid solutions at lower temperatures (400–1100 °C), exhibiting very nice reddish colourations associated to lower energy bandgaps (Eg below 2.30 eV). The obtained optimal compositions could be therefore alternative candidates as environmentally friendly reddish ceramic pigments.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of the European Ceramic Society - Volume 30, Issue 1, January 2010, Pages 37–52
نویسندگان
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