کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1477279 | 991178 | 2009 | 9 صفحه PDF | دانلود رایگان |
The crystal structure studies of aluminium titanate (Al2TiO5) in the temperature range of 25–1200 °C have been investigated by X-ray and neutron powder diffraction. The use of simultaneous refinement of the X-ray and neutron data has enhanced the refinement precision of the structure model of Al2TiO5 with the concomitant improvement in values such as atomic coordinates, site occupancies and unit-cell parameters. Results from Rietveld refinements showed that the disordering of Ti and Al atoms in the metal 1 and metal 2 sites. High-temperature neutron diffraction studies of the Al2TiO5 crystal structure revealed an increasing substitution of Al for the Ti atoms in the crystal structure. It is proposed that this increased substitution is responsible for the decomposition of Al2TiO5 that is observed between 900 and 1280 °C.
Journal: Journal of the European Ceramic Society - Volume 29, Issue 1, January 2009, Pages 67–75