کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1477431 991182 2008 7 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Tantalum doped 0.94Bi0.5Na0.5TiO3–0.06BaTiO3 piezoelectric ceramics
موضوعات مرتبط
مهندسی و علوم پایه مهندسی مواد سرامیک و کامپوزیت
پیش نمایش صفحه اول مقاله
Tantalum doped 0.94Bi0.5Na0.5TiO3–0.06BaTiO3 piezoelectric ceramics
چکیده انگلیسی

0.94(Bi0.5Na0.5)TiO3–0.06BaTiO3 (BNT6BT) ceramics doped with 0–4 mol.% tantalum were investigated in terms of the sintering, microstructure, phase transition, dielectric and piezoelectric properties. Tantalum doping has no remarkable effect on the microstructure and densification within the studied doping content. Up to 4 mol.% tantalum can dissolve into the lattice of BNT6BT ceramics, and the structure symmetry is not changed. However, a significant change in the dielectric behavior and piezoelectric properties took place. With increasing tantalum content, the antiferroelectric phase zone gets broader. Simultaneously, the temperature for a ferroelectric to antiferroelectric phase transition is clearly reduced, and the temperature for a transition from antiferroelectric phases to paraelectric phases is only a bit increased. The results indicate that tantalum occupies B site of a perovskite and behaves as a donor, generating A-site cation vacancies. The properties of the material thus become softer, concerning a reduced coercive field and an improved piezoelectric constant. More than 2 mol.% tantalum doping induces antiferroelectric properties, showing a typical double hysteresis loops, accompanied by a large maximum strain.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of the European Ceramic Society - Volume 28, Issue 4, 2008, Pages 871–877
نویسندگان
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