Synthesis of nano-titanium diboride powders by carbothermal reduction

The nano-sized titanium diboride particles were synthesized by carbothermal reduction process. In this study, carbothermal reduction process was used by controlling reaction rate and duration time. TiO2, B2O3 and carbon resin were used as starting materials with a molar composition; TiO2:B2O3:C = 1:2:5. The mixture was placed in a graphite crucible and pushed into a heating zone maintained at 1500 °C and Ar was flown for a period of 20 min. After reaction, the crucible was pulled out from the heating zone to cooling zone of the furnace for the rapid cooling. The average particle size of the agglomerated product was found to be ∼500 nm, which was composed with small primary particles of <100 nm in size. After milling, the large agglomerate was reduced to primary particles.