کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1478764 991235 2006 8 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Structural determination and microwave properties of (x)Re(Co1/2Ti1/2)O3-(1 − x)CaTiO3 (Re = La and Nd) solid solutions
موضوعات مرتبط
مهندسی و علوم پایه مهندسی مواد سرامیک و کامپوزیت
پیش نمایش صفحه اول مقاله
Structural determination and microwave properties of (x)Re(Co1/2Ti1/2)O3-(1 − x)CaTiO3 (Re = La and Nd) solid solutions
چکیده انگلیسی
Solid solutions of (x)Re(Co1/2Ti1/2)O3-(1 − x)CaTiO3 (Re = La and Nd, abbreviated to xLCT and xNCT, respectively) where x = 0, 0.25, 0.5, 0.75 and 1 have been fabricated using solid state synthesis. Samples have been examined using X-ray diffraction (XRD), scanning electron microscopy, transmission electron microscopy (TEM) and their dielectric properties measured at microwave (MW) frequencies. Formation of single phase solid solutions were confirmed by XRD and the measured lattice parameters varied linearly from LCT (a = 5.66 Å, b = 7.867 Å and c = 5.494 Å) and NCT (a = 5.636 Å, b = 7.914 Å and c = 5.461 Å) to CT (a = 5.596 Å, b = 7.731 Å and c = 5.424 Å). XRD and TEM confirmed both in-phase and antiphase rotations of O-octahedra consistent with an a−a−c+ tilt system across the entire solid solution series. Electron diffraction revealed that LCT and NCT have reflections associated with B-site cation ordering which is absent for x ≤ 0.75. MW dielectric measurements showed that LCT and NCT were highly insulating with microwave quality factor (Qf0) values of 39,000 and 34,000, respectively. Compositions anticipated to have a zero temperature coefficient of resonant frequency (τf) are 0.48LCT-CT and 0.52NCT-CT with ɛr = 45 and Qf0 ∼ 5000 and ɛr = 43 and Qf0 ∼ 4000, respectively.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of the European Ceramic Society - Volume 26, Issue 6, 2006, Pages 875-882
نویسندگان
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