کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1480320 | 1510404 | 2016 | 7 صفحه PDF | دانلود رایگان |
• Aerogel–aerogel composites for thermal insulation applications were synthesized.
• Highly insulating granular silica aerogel was embedded in a RF aerogel matrix.
• Plates up to 140 × 140 × 20 mm³ with a density of 0.19–0.27 g/cm³ were produced.
• Thermal conductivity of materials is between 0.026 and 0.053 W/mK.
• Composites are applicable at normal temperature range < 200 °C.
Aerogel–aerogel composites are prepared by embedding highly insulating granular silica aerogel (1–2 mm, 5–58 vol.%) into ambient pressure dried resorcinol-formaldehyde (RF) aerogel. The organic RF aerogel matrix is synthesized via a sol–gel reaction of resorcinol (1,3-dihydroxybenzene) and formaldehyde in deionized water with Na2CO3 as the catalyst. Plates around 90 × 195 mm² with a thickness of 19–25 mm are obtained and can be processed for application by sawing and grinding. A theoretical model for the volume-based surface area was used to show that the matrix aerogel around the silica aerogel grains is affected by their presence. Composites have a density 0.19 ≤ ρ ≤ 0.27 g/cm³ and a thermal conductivity at room temperature between 0.026 and 0.053 W/mK. Composites can be used as thermal insulation material in a normal temperature range < 200 °C due to the decomposition of the organic phase above 200 °C.
Journal: Journal of Non-Crystalline Solids - Volume 441, 1 June 2016, Pages 42–48