کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1481948 | 991549 | 2012 | 11 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: A 3-D numerical heat transfer model for silica aerogels based on the porous secondary nanoparticle aggregate structure A 3-D numerical heat transfer model for silica aerogels based on the porous secondary nanoparticle aggregate structure](/preview/png/1481948.png)
A 3-D finite volume numerical model based on the porous secondary nanoparticle random aggregate structure was developed to predict the total thermal conductivity of silica aerogels. An improved 3-D diffusion-limited cluster–cluster aggregation (DLCA) method was used to generate an approximately real silica aerogel structure. The model includes the effects of the random and irregular nanoparticle aggregate structure for silica aerogels, solid–gas coupling, combined conduction and radiation, nanoparticle and pore sizes, secondary nanoparticle porosity and contact length between adjacent nanoparticles. The results show that the contact length and porosity of the secondary aerogel nanoparticle significantly affect the aerogel microstructure for a give density and, thus, greatly affect the total thermal conductivity of silica aerogels. The present model is fully validated by experimental results and is much better than the model based on a periodic cubic array of full density primary nanoparticles, especially for higher densities. The minimum total thermal conductivity for various silica aerogel microstructures can be well predicted by the present model for various temperatures, pressures and densities.
► A 3-D numerical model is developed for the thermal conductivity of silica aerogels.
► 3-D random and irregular secondary nanoparticle aggregates represent silica aerogels.
► The minimum thermal conductivity for various aerogel structures can be predicted.
► The model provides theoretic guidelines for material designs with optimum parameters.
Journal: Journal of Non-Crystalline Solids - Volume 358, Issue 10, 15 May 2012, Pages 1287–1297