کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1482055 | 1510482 | 2011 | 7 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Enhancing mechanical properties of silica aerogels Enhancing mechanical properties of silica aerogels](/preview/png/1482055.png)
Low-density monolithic silica and hexylene-bridged polysilsesquioxane aerogels were chemical vapor deposition (CVD) treated with hexamethyldisilazane or hexachlorodisilane silylating agents producing TMS (trimethylsilane) or Si layers on the aerogel. Reinforcing the weak aerogels by controlled deposition process improved their compressive strength and preserved their properties characteristic of low-density aerogels. When the silica and hexylene-bridged polysilsesquioxane aerogels were CVD treated with hexamethyldisilazane, the compressive modulus more than doubled in some cases. However, when treating hexylene-bridged aerogels with hexachlorodisilane the compressive modulus increased six fold. Not only did CVD treatment of the aerogels improve the compressive modulus, but the low densities, high surface areas, high porosities, and the transparency of the aerogels were not significantly affected.
► Silica aerogels treated with HMDS more than doubled their compressive modulus.
Journal: Journal of Non-Crystalline Solids - Volume 357, Issues 19–20, October 2011, Pages 3435–3441