کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1482629 | 1510486 | 2010 | 5 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Fabrication of LiFePO4/carbon composites by glass powder crystallization processing and their battery performance
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موضوعات مرتبط
مهندسی و علوم پایه
مهندسی مواد
سرامیک و کامپوزیت
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چکیده انگلیسی
The glass powder crystallization processing is proposed to fabricate LiFePO4/carbon composites, in which the mixture of glass (33.3Li2O–33.3Fe2O3–33.3P2O5) powders and glucose or graphite was heat-treated at 560 ~ 800 °C in a nitrogen atmosphere. It is confirmed from an X-ray diffraction analysis and Raman scattering spectrum measurements that the glass crystallization is taking place together with the reduction of Fe3+ to Fe2+ and LiFePO4/carbon composites showing electrical conductivities of ~ 10−3 Scm− 1 are formed. The LiFePO4 glass-ceramics shows the voltage of 3.5 V and capacity of ~95 mAh/g. It is proposed that this new simple process has a potential for the fabrication of LiFePO4/carbon composites.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Non-Crystalline Solids - Volume 356, Issues 52–54, December 2010, Pages 3032–3036
Journal: Journal of Non-Crystalline Solids - Volume 356, Issues 52–54, December 2010, Pages 3032–3036
نویسندگان
Tsuyoshi Honma, Keita Hirose, Takayuki Komatsu, Takaya Sato, Shoko Marukane,