کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1482946 | 991582 | 2011 | 7 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Condensation of aluminosilicate gels—model system for geopolymer binders Condensation of aluminosilicate gels—model system for geopolymer binders](/preview/png/1482946.png)
The reaction of geopolymer binders can be subdivided into two more or less parallel reactions, (1) the dissolution of reactable silicate and aluminate monomers from the reactive solid material and (2) the condensation to an aluminosilicate gel. Due to the wide range of possible raw materials, the question arises whether the Si/Al ratio of the hardened aluminosilicate network is predominated by the Si/Al ratio of the raw materials, or a gel with preferred Si/Al ratio wants to condense. Therefore, aluminosilicate gels were synthesized with pure alkali silicate and alkali aluminate solutions. Two measurement series were started to investigate the influence of hydroxide concentration as well as the influence of Si/Al in the model system. The gels were characterized by chemical analysis, FT-IR spectroscopy, X-ray diffraction as well as 29Si and 27Al MAS NMR spectroscopy.
Research Highlights
► Influence of NaOH on precipitation of alumosilicate gel.
► Influence of Si/Al on precipitation of alumosilicate gel.
► Consequences for geopolymerization reaction.
Journal: Journal of Non-Crystalline Solids - Volume 357, Issue 5, 1 March 2011, Pages 1376–1382