کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1483808 1510548 2006 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Fabrication of mesoporous polymer/silica hybrid using surfactant-mediated sol–gel method
کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه مهندسی مواد سرامیک و کامپوزیت
پیش نمایش صفحه اول مقاله
Fabrication of mesoporous polymer/silica hybrid using surfactant-mediated sol–gel method
چکیده انگلیسی

A mesoporous polymer/silica hybrid was fabricated by a surfactant-mediated sol–gel method. Under our experimental conditions, acrylonitrile (AN) monomer was located at the exterior of micelles and the sol–gel reaction of tetraethoxyorthosilicate (TEOS) proceeded concurrently with the polymerization reaction of the AN monomer. In other words, the micelle/polyacrylonitrile/silica precursor was synthesized through the radical polymerization accompanied with a hydrolysis/condensation single reaction in a reaction system. This is a unique characteristic of our methodology, which embraces the concept of ‘micelle templating’. The pore diameter of the mesoporous polymer/silica hybrid could be tuned by varying the spacer length and concentration of surfactants. Furthermore, compared with conventional mesoporous carbons, the carbonized mesoporous polymer/silica hybrids displayed an enhanced electrical performance favorable for use as a supercapacitor.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Non-Crystalline Solids - Volume 352, Issues 38–39, 15 October 2006, Pages 3979–3984
نویسندگان
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