کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1484532 991634 2008 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Local structure and its effect on the oscillator strengths and emission properties of Ho3+ in chalcohalide glasses
موضوعات مرتبط
مهندسی و علوم پایه مهندسی مواد سرامیک و کامپوزیت
پیش نمایش صفحه اول مقاله
Local structure and its effect on the oscillator strengths and emission properties of Ho3+ in chalcohalide glasses
چکیده انگلیسی

The formation of structural units in Ge–Ga–S glass with CsBr addition and its effect on the optical band gap and several spectroscopic properties of Ho3+ were investigated. The optical band gap of the host glasses and the oscillator strengths of Ho3+ absorption decreased sharply when the ratio of CsBr/Ga became close to unity. These property changes were associated with the formation of structural units of [GaS3/2Br]− and they have a crucial effect on the changes of the local structure around Ho3+ ions. The local structure was not sensitive to the As or Br addition but was critically dependent on the concentration of CsBr.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Non-Crystalline Solids - Volume 354, Issue 27, 1 June 2008, Pages 3107–3112
نویسندگان
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