Investigation of gap states in phosphorous-doped ultra-thin a-Si:H by near-UV photoelectron spectroscopy

A variant of photoelectron spectroscopy with near-UV light excitation was established and applied to an n-type doping series of ultra-thin a-Si:H layers (layer thickness ∼10 nm). Using this technique, the position of the surface Fermi level EFs is obtained and the density of recombination active defect states in the a-Si:H band gap down to ∼1015 states/cm3 can be detected. Defect densities are generally about one order of magnitude higher than in the bulk of thicker (several 100 nm) layers, and the minimum achievable distance of EFs from the conduction band is ∼360 mV for doping with 104 ppm PH3. The optimum doping for the fabrication of solar cells is almost one order of magnitude lower. This discrepancy may be explained by enhanced recombination at the a-Si:H/c-Si interface at high doping levels, and in addition by an efficient recombination pathway where charge carriers tunnel from c-Si via a-Si:H band tail states into the a-Si:H and subsequently recombine at dangling bond states.