کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1484841 1510531 2007 5 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Peculiarities of dielectric relaxation in poly(vinylidene fluoride) with different thermal history
موضوعات مرتبط
مهندسی و علوم پایه مهندسی مواد سرامیک و کامپوزیت
پیش نمایش صفحه اول مقاله
Peculiarities of dielectric relaxation in poly(vinylidene fluoride) with different thermal history
چکیده انگلیسی
A method of broad-band dielectric relaxation spectroscopy (10−1-107 Hz) has been used to study the relaxation processes in the region of melting in two isotropic poly(vinylidene fluoride) films prepared by way of crystallization from melts under different conditions. The intensive relaxation process observed is attributed to manifestation of a space charge formed by extrinsic carriers. The relaxation time and the intensity of the process reduce when the crystallinity increases. This is related to the increase of extrinsic carriers' mobility in the amorphous areas. It is supposed that at isothermal crystallization there are more chemical defects (end groups, branches, HHTT-type defects) in amorphous areas. Such defects may impede compact chain packing in the amorphous domains and provide conditions for a higher level of mobility of free carriers.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Non-Crystalline Solids - Volume 353, Issues 47–51, 1 December 2007, Pages 4443-4447
نویسندگان
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