کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1484841 | 1510531 | 2007 | 5 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Peculiarities of dielectric relaxation in poly(vinylidene fluoride) with different thermal history
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی مواد
سرامیک و کامپوزیت
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چکیده انگلیسی
A method of broad-band dielectric relaxation spectroscopy (10â1-107Â Hz) has been used to study the relaxation processes in the region of melting in two isotropic poly(vinylidene fluoride) films prepared by way of crystallization from melts under different conditions. The intensive relaxation process observed is attributed to manifestation of a space charge formed by extrinsic carriers. The relaxation time and the intensity of the process reduce when the crystallinity increases. This is related to the increase of extrinsic carriers' mobility in the amorphous areas. It is supposed that at isothermal crystallization there are more chemical defects (end groups, branches, HHTT-type defects) in amorphous areas. Such defects may impede compact chain packing in the amorphous domains and provide conditions for a higher level of mobility of free carriers.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Non-Crystalline Solids - Volume 353, Issues 47â51, 1 December 2007, Pages 4443-4447
Journal: Journal of Non-Crystalline Solids - Volume 353, Issues 47â51, 1 December 2007, Pages 4443-4447
نویسندگان
V. Kochervinskii, I. Malyshkina, N. Gavrilova, S. Sulyanov, N. Bessonova,