کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1485022 1510529 2008 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Medium-range order in phospho-silicate bioactive glasses: Insights from MAS-NMR spectra, chemical durability experiments and molecular dynamics simulations
موضوعات مرتبط
مهندسی و علوم پایه مهندسی مواد سرامیک و کامپوزیت
پیش نمایش صفحه اول مقاله
Medium-range order in phospho-silicate bioactive glasses: Insights from MAS-NMR spectra, chemical durability experiments and molecular dynamics simulations
چکیده انگلیسی

The medium-range order of phospho-silicate bioactive glasses (with compositions (2 − p)SiO2 · 1Na2O · 1.1CaO · pP2O5, in which p = 0.10, 0.20, 0.26) has been studied by means of a combined-experimental (MAS-NMR, chemical durability measurements) and computational (classical molecular dynamics (MD)) approach. The structural model obtained by MD is showed to be helpful in the interpretation of the NMR spectra. A small amount of Si–O–P link units has been detected in glasses with low P2O5-content, but at high P2O5 concentration the percentage of Si–O–P bridges becomes important. However, Qn distributions show that the HP5 (p = 0.20) glass structure is less polymerized with respect to the H (p = 0.10) and HP6.5 (p = 0.26) glasses. These results provide useful explanation of the behavior of these glasses in water and highlight the influence of the medium-range order on a very important property of potential bioactive glasses such as the chemical durability.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Non-Crystalline Solids - Volume 354, Issues 2–9, 15 January 2008, Pages 84–89
نویسندگان
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