کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1485857 | 1510546 | 2006 | 5 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Non-ergodicity in a locally ordered fragile glass former Non-ergodicity in a locally ordered fragile glass former](/preview/png/1485857.png)
We measure the dynamic structure factor of m-toluidine through inelastic X-ray scattering in the mesoscopic Q range between 1 and 10 nm−1, where the static structure factor exhibits a prepeak resulting from a molecular spatial organization in nanometer size clusters, due to the formation of hydrogen bonds. We present experimental evidence of the square-root cusp in the temperature behavior of the non-ergodicity factor of m-toluidine which supports the view that the mode-coupling theory succeeds in describing the dynamics of supercooled molecular liquids, even for liquids with a local order, notwithstanding the cage formation is controlled by a mechanism different from the packing constraints typical of simple liquids. Moreover, we report on the behavior of the non-ergodicity factor in the low-temperature and wavevector regimes, finding a confirmation of the phenomenologic law proposed by Scopigno et al. [T. Scopigno, G. Ruocco, F. Sette, G. Monaco, Science 302 (2003) 849] which correlates the vibrational dynamics of the glass to the fragility of the supercooled liquid.
Journal: Journal of Non-Crystalline Solids - Volume 352, Issues 42–49, 15 November 2006, Pages 4531–4535