کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1486406 1510564 2005 8 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Do theories of glass transition that address only the α-relaxation need a new paradigm?
کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه مهندسی مواد سرامیک و کامپوزیت
پیش نمایش صفحه اول مقاله
Do theories of glass transition that address only the α-relaxation need a new paradigm?
چکیده انگلیسی

Experimental evidence is presented to show that temperature, volume and/or entropy enter earlier into the Johari–Goldstein (JG) relaxation to assert their influence on the mobility of molecules, long before the primary α-relaxation becomes known. Since the JG relaxation is the precursor of α-relaxation, a theory of glass transition needs reconsideration if it considers only the α-relaxation and it regards the α-relaxation as where originate the dependences of molecular mobility on temperature, volume and/or entropy. Actually, many-molecule dynamics transform the precursory JG relaxation to the terminal α-relaxation progressively with time. The stronger dependences of the α-relaxation time τα on temperature, volume and/or entropy are derived from the weaker dependences of the JG relaxation time τJG. A schematic solution of the glass transition problem based on the coupling model and the JG relaxation is proposed.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Non-Crystalline Solids - Volume 351, Issues 33–36, 15 September 2005, Pages 2635–2642
نویسندگان
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