کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1486443 | 1510564 | 2005 | 14 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Dielectric spectroscopy and micellization of aqueous solutions p-isononylphenoloxyethyleneglycolether
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موضوعات مرتبط
مهندسی و علوم پایه
مهندسی مواد
سرامیک و کامپوزیت
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Dielectric spectroscopy and micellization of aqueous solutions p-isononylphenoloxyethyleneglycolether Dielectric spectroscopy and micellization of aqueous solutions p-isononylphenoloxyethyleneglycolether](/preview/png/1486443.png)
چکیده انگلیسی
Dielectric relaxation spectra of optically isotropic aqueous solutions of p-isononylphenoldecaglycolether (NOP-10) were measured at 1.1Â MHz, 9.376Â GHz, 37.5Â GHz from 275 to 313Â K. The data were described assuming three Debye dispersion regions. Hydration numbers of NOP-10 molecules were calculated from an amplitude of the second dispersion region. Static permittivity values of the solutions were analyzed using theories for heterogeneous systems, and it was concluded that spheroidal micelles formed in the solutions at all investigated conditions. The shape of the micelles changed from prolate spheroids to spheres and then to oblate spheroids in the solutions with 9.97, 20, 30Â wt% of NOP-10 in the temperature range from 275 to 313Â K. A study of solutions with lower content of NOP-10 (1.14 and 4.97Â wt%) have been made from 275 to 351Â K, and it was deduced that in this case spherical micelles transformed to oblate spheroids and then to discs.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Non-Crystalline Solids - Volume 351, Issues 33â36, 15 September 2005, Pages 2868-2881
Journal: Journal of Non-Crystalline Solids - Volume 351, Issues 33â36, 15 September 2005, Pages 2868-2881
نویسندگان
T.M. Usacheva, N.V. Lifanova, V.I. Zhuravlev, V.K. Matveev,