کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1486673 1510562 2005 5 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Identification of a new form of monomeric vanadia species in silica gel
کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه مهندسی مواد سرامیک و کامپوزیت
پیش نمایش صفحه اول مقاله
Identification of a new form of monomeric vanadia species in silica gel
چکیده انگلیسی

A new form of isolated VO43- near mobile Na+ ions in silica gel, but without strong V–O–Si linkages unlike the previously reported isolated monomeric vanadia species, was identified. Our VO43- species have motionally averaged NMR spectra mainly resulting from mobile Na+ ions nearby rather than the dynamics of VO43- species themselves. This VO43- species as well as NaVO3 · 1.89H2O were produced, upon aging, from decavanadate ions in vanadia–silica composite gel with V/(V + Si) = 2.3%. In addition, this work demonstrates the usefulness of the employing multinuclear solid state NMR and XRD techniques together for the characterization of inhomogeneous nano-composite materials.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Non-Crystalline Solids - Volume 351, Issues 40–42, 15 October 2005, Pages 3365–3369
نویسندگان
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