کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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1486717 | 1510565 | 2005 | 4 صفحه PDF | دانلود رایگان |
Light scattering in glasses is due to inhomogeneities described as density fluctuations and concentration fluctuations. Both fluctuations are characterized by fictive and chemical fictive temperatures, Tf and Tf′ respectively. A SiO2–Al2O3–P2O5 fiber amplifier glass doped with Er3+ is studied. From Raman scattering the fictive temperature of a fiber is determined to be 130 °C higher than in a preform. In situ small angle X-rays scattering (SAXS) measurements on a sample with an initial fictive temperature of 1100 °C show a structural relaxation below Tg and no evidence of evolution of concentration fluctuations up to 1400 °C. These measurements demonstrate that in a strong glass such as that considered in this work, Tf and Tf′ can be monitored separately allowing a high Tf′ favouring the dispersion of the doping ions and a low Tf decreasing the Rayleigh scattering and increasing the transmission of the signal.
Journal: Journal of Non-Crystalline Solids - Volume 351, Issues 30–32, 1 September 2005, Pages 2421–2424