کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1494066 | 992899 | 2014 | 5 صفحه PDF | دانلود رایگان |
• The evidences of multisite structure of Ce3+ dopant in LuAG scintillation material.
• The evidences of the lattice expansion of LuAG under influence of RE antisites.
• Estimated concentration of antisite defects equals to 1.2% of the Al3+ sites.
Low temperature, infrared transmission spectra of lutetium aluminum garnet (LuAG) bulk crystals and epitaxial layers doped with Ce are presented. In the region of intra-configurational 4f–4f transitions the spectra of the bulk LuAG crystal exhibit the signatures of several different Ce3+ related centers. Apart from the dominant center, associated with Ce substituting lutetium, at least six other centers are found, some of them attributed to so-called antisite locations of rare-earth ions in the garnet host, i.e., ions in the Al positions. X-ray diffraction data prove lattice expansion of bulk LuAG crystals due presence of rare-earth antisites.
Journal: Optical Materials - Volume 36, Issue 9, July 2014, Pages 1515–1519