کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1494068 | 992899 | 2014 | 9 صفحه PDF | دانلود رایگان |
• Large shifts of emission spectra indicated CT complex formation.
• Photoinduced energy/electron transfer from BT1 dye to fullerene occurred.
• BT1 dopant favored CT possibility in P3HT:BT1:PC61BM ternary blend.
Three electron-deficient small molecules based on 2,1,3-benzothiadiazole (BTD) units namely, 4,7-bis(3-methoxyphenyl)-2,1,3-benzothiadiazole (BT1), (3-{7-[3-(dimethylamino)phenyl]-2,1,3-benzothiadiazole-4-yl}phenyl)dimethylamine (BT2) and 3,3′-(2,1,3-benzothiadiazole-4,7-dyl)dianiline (BT3) were synthesized and their photophysical properties were investigated systematically to understand their potential usage in ternary organic solar cells (OSCs) as additive material to enhance the cell efficiency. All these molecules show broad absorption bands in 350–750 nm on glass substrate and their optical band gaps were calculated to be around 2.50–2.80 eV. BTD fluorescence dynamics were measured in polymer:BT1:fullerene blends with varying emission wavelengths of active layer. Fluorescence emission and time resolved measurements indicated photoinduced energy shift from BT1 dye to fullerene and also from polymer to BT1 dye upon excitation of the active layer.
Figure optionsDownload high-quality image (66 K)Download as PowerPoint slide
Journal: Optical Materials - Volume 36, Issue 9, July 2014, Pages 1525–1533