کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1495101 | 992926 | 2012 | 7 صفحه PDF | دانلود رایگان |
A promising heteroleptic iridium complex with carbazole-functionalized substituent, i.e., (cbbt)2Ir(acac), in which cbbt was 2-(4-(4-(9H-carbazol-9-yl)butoxy)phenyl)benzo[d]thiazole and acac acetylacetonate, was designed, synthesized and structurally characterized. The complex emitted intensely orange phosphorescence upon photoexcitation with high luminescent quantum efficiency (0.30), short triplet lifetime (0.15 μs) and high decomposition temperature (310 °C). The electronic properties of (cbbt)2Ir(acac) were also examined according to the density functional theory calculations. Organic light-emitting diodes using (cbbt)2Ir(acac) as doped emitter exhibited orange electrophosphorescence with prominent performances. An extremely high brightness of 17,910 cd m−2 at a high voltage (17 V) and a maximum luminance efficiency of 25.5 cd A−1 were achieved. More importantly, those devices exhibited low efficiency roll-off of 30–35% from 10 to 100 mA cm−2, which was probably attributed to the short triplet lifetime of (cbbt)2Ir(acac).
Figure optionsDownload high-quality image (111 K)Download as PowerPoint slideHighlights
► A promising carbazole-functionalized Ir(III) complex was synthesized and characterized.
► The complex emitted intensely orange phosphorescence with very short lifetime (0.15 μs).
► Its electronic properties were examined according to DFT calculations.
► The devices using the complex as doped emitter exhibited excellent performances.
Journal: Optical Materials - Volume 35, Issue 2, December 2012, Pages 300–306