کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1495791 | 992945 | 2011 | 4 صفحه PDF | دانلود رایگان |

Creation of bismuth-containing near-infrared (NIR) luminescent centers by synproportionation reaction of Bi3+ and Bi0 was demonstrated in borate and phosphate glasses. This finding is discussed in the light of low-valence nature of bismuth NIR-luminescent centers. The experimental data is consistent with the hypothesis of univalent Bi+ (and, possible, subvalent cluster Bi ions) as a source of NIR luminescence. The dependence of Bi luminescent centers stability on oxoacidity of glass melts was discussed.
Research highlights
► Subvalent bismuth species possess NIR luminescence in glass matrices.
► Luminescent centers prepared by Bi3+ reaction with Bi metal in glass melt.
► High oxoacidity of melt is required for luminescent centers stabilization.
Journal: Optical Materials - Volume 33, Issue 4, February 2011, Pages 631–634