کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1495791 992945 2011 4 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
On the origin of near-IR luminescence in Bi-doped materials (I). Generation of low-valence bismuth species by Bi3+ and Bi0 synproportionation
کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه مهندسی مواد سرامیک و کامپوزیت
پیش نمایش صفحه اول مقاله
On the origin of near-IR luminescence in Bi-doped materials (I). Generation of low-valence bismuth species by Bi3+ and Bi0 synproportionation
چکیده انگلیسی

Creation of bismuth-containing near-infrared (NIR) luminescent centers by synproportionation reaction of Bi3+ and Bi0 was demonstrated in borate and phosphate glasses. This finding is discussed in the light of low-valence nature of bismuth NIR-luminescent centers. The experimental data is consistent with the hypothesis of univalent Bi+ (and, possible, subvalent cluster Bi ions) as a source of NIR luminescence. The dependence of Bi luminescent centers stability on oxoacidity of glass melts was discussed.

Research highlights
► Subvalent bismuth species possess NIR luminescence in glass matrices.
► Luminescent centers prepared by Bi3+ reaction with Bi metal in glass melt.
► High oxoacidity of melt is required for luminescent centers stabilization.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Optical Materials - Volume 33, Issue 4, February 2011, Pages 631–634
نویسندگان
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