کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1495932 992950 2010 7 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Effect of microstructure on the radioluminescence and transparency of Ce-doped strontium hafnate ceramics
موضوعات مرتبط
مهندسی و علوم پایه مهندسی مواد سرامیک و کامپوزیت
پیش نمایش صفحه اول مقاله
Effect of microstructure on the radioluminescence and transparency of Ce-doped strontium hafnate ceramics
چکیده انگلیسی

In this paper we report on the fabrication and characterization of SrHfO3:Ce ceramics. Powders were prepared by solid-state synthesis using metal oxides and carbonates. X-ray diffraction measurements showed that phase-pure SrHfO3 is formed at 1200 °C. Inductively coupled plasma spectroscopy confirmed the purity and composition of each batch. SrHfO3 exhibits several phase changes in the solid, but this does not appear to be detrimental to the ceramics. Microprobe experiments showed uniform elemental grain composition, whereas aluminum added as charge compensation for trivalent cerium congregated at grain boundaries and triple points. Radioluminescence spectra revealed that the light yield decreases when the concentration of excess Sr increases. The decrease in the light yield may be related to the change of Ce3+ into Ce4+ ions. For stoichiometric SrHfO3:Ce, the light yield is about four times that of bismuth germanate (BGO), the conventional benchmark, indicating great potential for many scintillator applications.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Optical Materials - Volume 33, Issue 1, November 2010, Pages 84–90
نویسندگان
, , , , , , , , , ,