Effective holographic recordings in the photopolymer nanocomposites with functionalized silica nanoparticle and polyurethane matrix

Effective holographic nanocomposites were developed by the surface-functionalized silica nanoparticles and two acrylate monomers/polyurethane (PU) matrix polymer. The functionalization was done with silane compounds carrying long alkyl chain or vinyl group. We evaluated the holographic nanocomposite films by the diffraction efficiency, volume shrinkage, optical loss, and the film morphology. It was found that acrylate monomers/PU system gave higher diffraction efficiency than those of two monomers due to the high refractive index mismatch between the acrylate-rich and PU-rich regions. With the modification of silica particle, up to 35% of particle loading was possible to give a maximum diffraction efficiency of 93.6% for a film of 20 μm in thickness, along with improved refractive index modulation and the sensitivity.

► We made holographic nanocomposites by functionalized silica nanoparticles.
► Polyurethane was also used as matrix polymer.
► Silica was modified with silane compounds carrying long alkyl chain or vinyl group.
► High diffraction efficiency and sensitivity were achieved at high particle loading.
► Low volume shrinkage and optical loss were also achieved.