کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1496101 | 992954 | 2009 | 8 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Media effects on the optical properties of proton donor group containing azobenzene derivatives
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی مواد
سرامیک و کامپوزیت
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Media effects on the optical properties of proton donor group containing azobenzene derivatives Media effects on the optical properties of proton donor group containing azobenzene derivatives](/preview/png/1496101.png)
چکیده انگلیسی
A series of hydroxy and carboxy group containing azobenzene compounds were synthesized and investigated by UV-vis and fluorescence spectroscopy. It could be shown that the ambient medium exerted a strong influence on the absorption behavior and the trans-cis isomerization behavior of the azo compounds. Especially in the case of hydroxy group functionalized azobenzenes, deprotonation with NaOH or a polymeric base changed the spectral behavior of the compounds remarkably. A strong bathochromic shift of the dyes' longest wavelength absorption band was observed. Furthermore, the influence of different solvents and different polymeric matrices on the trans-cis isomerization behavior of the azobenzenes was investigated. The results are discussed in terms of utilization of the azo dyes as probe molecules for interactions in polymer blends.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Optical Materials - Volume 32, Issue 1, November 2009, Pages 54-61
Journal: Optical Materials - Volume 32, Issue 1, November 2009, Pages 54-61
نویسندگان
Ulrich Oertel, Hasan Mart, Hartmut Komber, Frank Böhme,