کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1496384 | 992961 | 2009 | 6 صفحه PDF | دانلود رایگان |
Emission spectra at 10 K employing synchrotron radiation have been recorded for the tripositive lanthanide ions, Ln = Sm, Gd, Tb, Ho, and Er situated at octahedral (or nearly octahedral) site symmetry in hexafluoroelpasolite Cs2NaMF6 (M = Y, Sc, or Ga) lattices. Interconfigurational 5d → 4f transitions are only observed for Er3+, and the intensity ratio of 4f105d → 4f11 emission, compared with 4f11 → 4f11 emission, with excitation into 5d levels, is greater for M = Ga than M = Sc. The highest energy intraconfigurational emission is from 4G5/2 (Sm3+), 6P7/2 (Gd3+), 5D3 (Tb3+), 5G4 (Ho3+), and 2F(2)7/2 (Er3+). Detailed energy level assignments have been given for Ln = Sm, Gd, and the remaining spectra are assigned as multiplet–multiplet transitions.
Journal: Optical Materials - Volume 31, Issue 11, September 2009, Pages 1729–1734