Magnetic, Mössbauer and optical spectroscopic properties of the AFe3O(PO4)3 (A = Ca, Sr, Pb) series of powder compounds

• Three FM-like 2nd order phase transitions in AFe3O(PO4)3 (A = Ca, Sr, Pb) powders.
• Existence of 3 crystallographically non equivalent Fe3+ sites and two 2nd order MPTs.
• First proposition of Tanabe–Sugano diagram of PbFe3O(PO4)3 and SrFe3O(PO4)3.

AFe3O(PO4)3 (A = Ca, Sr and Pb) powder compounds were studied by means of X-ray diffraction (XRD), electron-probe microanalysis (EPMA) coupled with wavelength dispersion spectroscopy (WDS), Raman and diffuse reflectance spectroscopies, specific heat and magnetic properties measurements. Magnetization, magnetic susceptibility and specific heat measurements carried out on AFe3O(PO4)3 (A = Sr, Ca and Pb) powders firmly establish a series of three ferromagnetic (FM)-like second order phase transitions spanned over the 32–8 K temperature range. Room temperature Mössbauer spectroscopy and associated DFT calculations confirm the existence of three crystallographically non equivalent Fe3+ sites in the three compounds. Mössbauer spectra recorded as a function of temperature in the PbFe3O(PO4)3 compound also establishes the occurrence of two purely magnetic and reversible phase transitions at 32 and 10 K. Diffuse reflectance measurements reveal two broad absorption bands at 1047 and 837 nm, in both PbFe3O(PO4)3 and SrFe3O(PO4)3 powders, with peak cross sections ∼10−20 cm2 typical of spin-forbidden and forced electric dipole intraconfigurational transitions.

Series of ferromagnetic-like phase transitions discovered in the AFe3O(PO4)3 (A = Ca, Sr, Pb) powder compounds by ZFC/FC magnetization measurements.Figure optionsDownload as PowerPoint slide