کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1506017 993779 2010 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
A Mössbauer spectroscopy investigation of SrFe1−xScxO3−δ perovskites
موضوعات مرتبط
مهندسی و علوم پایه مهندسی مواد سرامیک و کامپوزیت
پیش نمایش صفحه اول مقاله
A Mössbauer spectroscopy investigation of SrFe1−xScxO3−δ perovskites
چکیده انگلیسی

Polycrystalline samples of oxygen deficient perovskites SrFe1−xScxO3−δ (0 ≤ x ≤ 0.5) have been synthesized by direct solid state reactions. Each compound has been stabilized with two different oxygen stoichiometries. The structural study shows, firstly, the good cationic homogeneity of the samples and, secondly, that the Sc and Fe atoms are randomly distributed over the same crystallographic site, whatever the scandium content. This implies that no anionic order is possible. A detailed Mossbauer spectroscopy study clearly shows that the substitution of scandium for iron involves an oxygen content decrease which decreases the tetravalent iron content until its total disappearance for x = 0.5. The evolutions of the isomer shift, the quadrupolar splitting and the relative intensity versus the Sc3+ content are depicted in the present paper.

Figure 6. Isomer shifts (up) and Mössbauer relative intensities (down) versus scandium content of the contributions used to fit the spectra of the as-prepared SrFe1−xScxO3−δ samples.Figure optionsDownload as PowerPoint slide

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Solid State Sciences - Volume 12, Issue 5, May 2010, Pages 739–744
نویسندگان
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