کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1506253 993786 2008 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Neutron, synchrotron X-ray diffraction and X-ray absorption studies of CaLaFeMnO6 double perovskite
موضوعات مرتبط
مهندسی و علوم پایه مهندسی مواد سرامیک و کامپوزیت
پیش نمایش صفحه اول مقاله
Neutron, synchrotron X-ray diffraction and X-ray absorption studies of CaLaFeMnO6 double perovskite
چکیده انگلیسی

High-resolution neutron and synchrotron X-ray powder diffraction data of CaLaFeMnO6 double perovskite have been used in a joint Rietveld refinement method to obtain accurate room temperature structure which includes a precise set of atomic positions and thermal motion parameters. The valence states of Mn and Fe in the octahedra were also determined by X-ray absorption spectroscopy by measuring Mn and Fe K edges at room temperature. The simultaneous refinement of both synchrotron X-ray and neutron diffraction data reaffirmed that the system indeed possesses orthorhombic structure with space group Pbnm. X-ray absorption spectroscopic measurements reveal that both Mn and Fe occupy the octahedral sites with valence state of +4 and +3, respectively. No cationic ordering arrangement was found and Fe/Mn was found to be randomly distributed over the octahedral sites. The results agree well with the earlier published neutron diffraction data.

Polyhedral view along (001) of the LaCaMnFeO6 double perovskite system determined by the joint refinement of high-resolution neutron and synchrotron X-ray diffraction data using Rietveld refinement method.Figure optionsDownload as PowerPoint slide

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Solid State Sciences - Volume 10, Issue 11, November 2008, Pages 1634–1639
نویسندگان
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