کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1506384 | 993792 | 2010 | 4 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: High-yield synthesis of quantum-confined CdS nanorods using a new dimeric cadmium(II) complex of S-benzyldithiocarbazate as single-source molecular precursor High-yield synthesis of quantum-confined CdS nanorods using a new dimeric cadmium(II) complex of S-benzyldithiocarbazate as single-source molecular precursor](/preview/png/1506384.png)
A convenient solvothermal single-source route has been developed for the bulk synthesis of CdS nanorods using new air stable dimeric cadmium(II) complex of S-benzyldithiocarbazate, [Cd(PhCH2SC(S)NHNH2)Cl2]2, at a relatively low temperature. The decomposition of the precursor was made by heating at 160 °C in hexamethylenediamine (HMDA) to give amine capped CdS nanocrystals having yield ca. 90%; nano-dimensional rods are clearly visible in transmission electron microscope (TEM). The nanorods have been further characterized by X-ray diffraction (XRD), energy dispersed X-ray spectroscopy (EDX), FTIR and optical measurements. The structure of precursor was also established by single crystal X-ray crystallography.
Figure optionsDownload as PowerPoint slide
Journal: Solid State Sciences - Volume 12, Issue 4, April 2010, Pages 532–535