کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1506697 | 993805 | 2008 | 7 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
A new lithium vanadyl diphosphate Li2VOP2O7: Synthesis and electrochemical study
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موضوعات مرتبط
مهندسی و علوم پایه
مهندسی مواد
سرامیک و کامپوزیت
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چکیده انگلیسی
A new vanadium diphosphate, Li2VOP2O7, has been synthesized by ion exchange from Na2VOP2O7, using an eutectic mixture of {0.4LiOH·H2O–0.6LiNO3} at 200 °C. It crystallizes in space group P21/c, with the lattice parameters a = 7.4674(8) Å, b = 12.442(2) Å, c = 6.2105(7) Å and β = 97.79(1)°. The crystal structure of Li2VOP2O7, refined by powder X-ray diffraction data, shows that the structure of the parent Na-phase is retained but a prominent decrease in the layer spacing is observed. Li2VOP2O7 has been tested as a cathode material for Li-ion battery. One lithium is deintercalated by charging to 4.6 V, however, on discharge only about 0.5 Li is re-intercalated.
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ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Solid State Sciences - Volume 10, Issue 10, October 2008, Pages 1285–1291
Journal: Solid State Sciences - Volume 10, Issue 10, October 2008, Pages 1285–1291
نویسندگان
M. Satya Kishore, V. Pralong, V. Caignaert, U.V. Varadaraju, B. Raveau,