کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1507158 993841 2006 7 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Crystal structure and magnetic properties of Co7(TeO3)4Br6—a new cobalt tellurite bromide
موضوعات مرتبط
مهندسی و علوم پایه مهندسی مواد سرامیک و کامپوزیت
پیش نمایش صفحه اول مقاله
Crystal structure and magnetic properties of Co7(TeO3)4Br6—a new cobalt tellurite bromide
چکیده انگلیسی

The crystal structure of the new compound Co7(TeO3)4Br6 is described together with the magnetic properties. The new compound crystallizes in the monoclinic space group C2/c with the unit cell parameters a=20.6532(5) Åa=20.6532(5) Å, b=8.6533(2) Åb=8.6533(2) Å, c=14.7262(5) Åc=14.7262(5) Å, β=124.897(3)°β=124.897(3)°, Z=4Z=4. The crystal structure was solved from single crystal data, R=0.0242R=0.0242. The structure can be considered as layered and the building units are [CoO4Br2] and [CoO2Br4] octahedra and [TeO3E] tetrahedra, E being the 5s2 lone pair on the Te(IV) ions. The magnetic properties of the compound are characterised by antiferromagnetic correlations at high temperatures, strong deviation from the Curie–Weiss behaviour in a broad intermediate temperature range and long range magnetic ordering setting-in at low temperatures. Magnetic ordering takes place in stages, being represented by two susceptibility anomalies, at TN=33 KTN=33 K and TC=27 KTC=27 K. The magnetic transition at TCTC is ferromagnetic (or ferrimagnetic) in character.

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ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Solid State Sciences - Volume 8, Issue 7, July 2006, Pages 836–842
نویسندگان
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