کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1515431 | 1511518 | 2015 | 6 صفحه PDF | دانلود رایگان |
• CdS-loaded TiO2 microsphere with highly exposed (001) facet is synthesized.
• CdS/TiO2 microsphere exhibits excellent photocatalytic H2-production efficiency.
• (001) faceted surface is beneficial for the interfacial transfer of electron.
CdS-loaded TiO2 microspheres with highly exposed (001) facets were prepared by hydrothermal treatment of a TiF4–HCl–H2O mixed solution followed by a chemical bath deposition of CdS onto TiO2 microspheres. The crystal structure, surficial micro-structure and photo-absorption property of the samples were characterized by XRD, FE-SEM, TEM and UV–vis diffuse reflectance spectroscopy, etc. The as-prepared samples exhibited superior visible-light-driven photocatalytic H2-production activity from lactic acid aqueous solution in comparison with CdS-sensitized TiO2 nanoparticles, whose surface was dominated by (101) facets. Photoelectrochemical measurement confirmed that (001) facet is beneficial for the transfer of photo-generated electron from CdS to TiO2 microsphere, which led to the unexpected high photocatalytic activity of CdS-loaded TiO2 microspheres.
Journal: Journal of Physics and Chemistry of Solids - Volume 87, December 2015, Pages 171–176