Facile decolorization of methylene blue by morphology-dependence δ-MnO2 nanosheets -modified diatomite

• Birnessite MnO2@coscinodiscus-diatomite and melosira-diatomites.
• Good cycling stability: 80% removal rate after 2nd cycle.
• Higher removal rate: 81–91% in 2 h.
• Fabrication strategy: one-pot and scalable without any surfactants.

In this work, coscinodiscus-diatomite and melosira-diatomite have been decorated by ultrathin birnessite MnO2 (δ-MnO2) nanosheets through a one-pot hydrothermal method without using any surfactants. The δ-MnO2 nanosheets are observed to grow vertically on the purified melosira-diatomite as well as coscinodiscus-diatomite. Moreover, the two composites exhibit high efficiency for decomposing methylene blue (MB) in the presence of H2O2. The coscinodiscus-diatmite@MnO2 achieves a removal rate of 81.8% (2 h), and yet melosira-diatomite@MnO2 reaches a higher degradation rate of 91.3% in 2 h. Additionally, the effects of catalyst amount, catalysis reaction temperature, preparing time have also been investigated. In principle, the diverse diatomite@MnO2 nanostructures not only present an environmentally friendly and low cost with a good cycling stability, but also offer a simple way for the catalytic degradation of dye waste water in practical applications.

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