کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1515677 1511526 2015 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Hyperfine interactions in and lattice parameters of pyrochlore and defect fluorite (Eu1−xNdx)2Zr2O7
موضوعات مرتبط
مهندسی و علوم پایه مهندسی مواد مواد الکترونیکی، نوری و مغناطیسی
پیش نمایش صفحه اول مقاله
Hyperfine interactions in and lattice parameters of pyrochlore and defect fluorite (Eu1−xNdx)2Zr2O7
چکیده انگلیسی
Pyrochlore and defect fluorite (Eu1−xNdx)2Zr2O7 compounds (x=0, 0.5 and 0.75) synthesized by a wet chemical approach were investigated using temperature dependent high energy X-ray diffraction as well as 151Eu Mössbauer spectroscopy. Diffraction data reveals an increase in lattice parameter with increasing Nd content, an increase that is disproportionally large between x=0.5 and 0.75. The 151Eu Mössbauer spectral parameters, i.e. isomer shift and quadrupole splitting, fall in separate regions for pyrochlore and defect fluorite type compounds. Between 80 and 350 K, the impact of the order-disorder, i.e. pyrochlore to defect fluorite, transition on isomer shift and quadrupole splitting is found to exceed the one due to lattice expansion.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Physics and Chemistry of Solids - Volume 79, April 2015, Pages 43-48
نویسندگان
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