کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1515786 | 1511527 | 2015 | 9 صفحه PDF | دانلود رایگان |
• Niobium oxide and hydroxide were reduced by calcium dissolved in CaCl2 melt.
• Sub-micrometer spherical metallic particles with coral-like morphology were obtained.
• High capacitance (CV) because of small shrinkage during sintering.
Metallic niobium powder was produced for applications in electric capacitors via calciothermic reduction of niobium hydroxide in molten CaCl2. Sub-micrometer spherical metallic particles with coral-like morphologies reflected the particle size of the starting oxide powder. A fine powder was obtained from the mixtures of niobium hydroxide and CaO or Ca(OH)2, respectively.Sintered pellets of the metallic powder showed a higher capacitance (CV) than those of the simply reduced powder without pre-treatment, because the shrinkage during sintering was smaller. The CV was as large as that of commercially sintered pellets for tantalum capacitors. Therefore, this niobium powder would act as a higher-voltage capacitor by applying chemical anodic treatment at higher voltages, and lower oxygen content in the reduced power could realize a lower leak current.
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Journal: Journal of Physics and Chemistry of Solids - Volume 78, March 2015, Pages 101–109