کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1516512 1511570 2011 14 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Theoretical and experimental study of structures and properties of cement paste: The nanostructural aspects of C–S–H
موضوعات مرتبط
مهندسی و علوم پایه مهندسی مواد مواد الکترونیکی، نوری و مغناطیسی
پیش نمایش صفحه اول مقاله
Theoretical and experimental study of structures and properties of cement paste: The nanostructural aspects of C–S–H
چکیده انگلیسی

Ordinary Portland cement (OPC) paste with water to cement ratio 0.5 has been studied by FTIR spectroscopy and TEM/SAED techniques. The progressive shift in frequencies and change in intensity of characteristic peaks in the FTIR spectra of cement powder indicate polymerization of silicates due to hydration reaction. The appearance of new peaks around 975–985 and 3640–3650 cm−1 in FTIR spectra of cement paste has been attributed to the formation of two principal hydration products (C–S–H) and Ca(OH)2, respectively. There is a strong resemblance of peak shape at 980 cm−1 of cement paste with that of synthesized 1.1 nm Tobermorite. TEM/SAED techniques reveal the presence of three distinct types of C–S–H nanostructures viz. spherical particles, fibres and bundle of fibres, and nano tubes in cement paste. Theoretical study of two C–S–H clusters by MNDO and Density Functional Techniques shows excellent agreement between computed structural data and reported experimental results of Tobermorite and Jennite. The computed interplanar Ca–Ca distance (11.162 Å) of C–S–H cluster (Ca/Si=1.125) indicates greater structural similarity of this cluster to 11 Å Tobermorite. There is a strong similarity of IR profile of C–S–H cluster (Ca/Si=1.125) with 1.1 nm Tobermorite. Above study indicates that this cluster is probably the most likely basic unit of C–S–H phases formed during the early stage of OPC cement hydration.


► Key FTIR peaks of OPC cement are identified.
► Key FTIR peaks of major cement hydration products C–S–H and Ca(OH)2 identified.
► C–S–H nanostructures with different state of crystallinity observed in cement paste.
► Theoretical study of structure and properties of models for C–S–H nanophases.
► [P–Ca–P] cluster could be the probable model for cementitious C–S–H nanophases.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Physics and Chemistry of Solids - Volume 72, Issue 8, August 2011, Pages 920–933
نویسندگان
, ,