کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1517071 | 1511602 | 2008 | 6 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Solid-state NMR study of bioactive binary borosilicate glasses
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی مواد
مواد الکترونیکی، نوری و مغناطیسی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
A series of binary borosilicate glasses prepared by the sol-gel method are shown to be bioactive. Tetraethyl orthosilicate (TEOS) and trimethylborate (TMB) in acidic medium are used to prepare xB2O3·(1âx)SiO2 glass systems for x=0.045-0.167. The formation of a layer of apatite-like mineral on the glass surface becomes apparent after soaking in simulated body fluid for 48 h. We have measured the 11B-11B homonuclear second moments of the borosilicate glasses and inferred that no macroscopic phase separation occurred in our glasses. The 11B chemical shift data also show that the formation of clustered boroxol rings is negligible in our glass system. Although the bioactivity of our borosilicate glasses is less than that of CaO-SiO2 sol-gel glasses, these simple binary systems could be taken as reference glass systems for the search of new bioactive borosilicate glasses.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Physics and Chemistry of Solids - Volume 69, Issue 11, November 2008, Pages 2628-2633
Journal: Journal of Physics and Chemistry of Solids - Volume 69, Issue 11, November 2008, Pages 2628-2633
نویسندگان
Tim W.T. Tsai, Yun Mou, Yao-Hung Tseng, Long Zhang, Jerry C.C. Chan,