کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1517484 | 1511587 | 2010 | 5 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
2H and 13C NMR studies of molecular orientation and dynamics in liquid crystal 6BA
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی مواد
مواد الکترونیکی، نوری و مغناطیسی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
The dynamics and orientation of dimers accompanying the formation and destruction of hydrogen bonds in the nematic phases of 4-n-hexylbenzoic acid (6BA) were studied by 13C and 2H NMR. The orientational order parameter S in the nematic phase was estimated from the quadrupole splitting of the 2H NMR spectrum. The intermolecular interaction energy for the molecular order in the nematic phase decreased with increasing temperature. The flexibility of dimers due to the destruction of the hydrogen bond is closely related to a decrease in the intermolecular interaction energy. The proportion of 2H NMR spin-lattice relaxation time (T1) to S, which reveals the coupling of the orientational fluctuations with the hydrogen bonding processes, was observed.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Physics and Chemistry of Solids - Volume 71, Issue 3, March 2010, Pages 389-393
Journal: Journal of Physics and Chemistry of Solids - Volume 71, Issue 3, March 2010, Pages 389-393
نویسندگان
You Suzuki, Takashi Uta, Tomonori Ida, Motohiro Mizuno, Miwa Murakami, Masataka Tansho, Tadashi Shimizu,