کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1518456 | 1511617 | 2007 | 5 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Structural and electrochemical study of Cr-substituted layered manganese oxide cathode materials
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی مواد
مواد الکترونیکی، نوری و مغناطیسی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
A lithiated layered Mn–Cr compound, Li[Cr0.29Li0.24Mn0.47]O2 was synthesized by a solution method with subsequent quenching. The crystal structure was investigated by X-ray diffraction (Rietveld refinement) and Electron diffraction showing co-existence of rhombohedral and monoclinic structures. According to the co-indexed electron diffraction patterns and HRTEM images, Li[Cr0.29Li0.24Mn0.47]O2 electrode was composed of nano-scale domains indexed in monoclinic and hexagonal structures, simultaneously. The nano-composite cathode successfully prevents spinel-like structural transformation during cycling and delivered a good reversible capacity of about 195 mAh/g between 2.4 and 4.7 V.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Physics and Chemistry of Solids - Volume 68, Issues 5–6, May–June 2007, Pages 1126–1130
Journal: Journal of Physics and Chemistry of Solids - Volume 68, Issues 5–6, May–June 2007, Pages 1126–1130
نویسندگان
C.W. Park, I. Ruth Mangani, H.W. Ryu, C.J. Park, J.S. Lee, S.J. Song, J.H. Moon, J. Kim,