کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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1518561 | 1511606 | 2008 | 8 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Optical properties of sol–gel fabricated Ni/SiO2 glass nanocomposites Optical properties of sol–gel fabricated Ni/SiO2 glass nanocomposites](/preview/png/1518561.png)
Nickel nanoparticles were grown in silica glass by annealing of the sol–gel prepared silicate matrices doped with nickel nitrate. TEM characterization of Ni/SiO2 glass proves the formation of isolated spherical nickel nanoparticles with mean sizes 6.7 and 20 nm depending on annealing conditions. The absorption and photoluminescence spectra of Ni/SiO2 glasses were measured. In the absorption spectra, we observed the band related to the surface plasmon resonance (SPR) in Ni nanoparticles. The broadening of SPR was observed with decrease of Ni nanoparticle size. The width of the surface plasmon band decreases 1.5 times at the lowering of temperature from 293 to 2 K because of strong electron–phonon interaction. The spectra proved the creation of nickel oxide NiO clusters and Ni2+ ions in silica glass as well.
Journal: Journal of Physics and Chemistry of Solids - Volume 69, Issue 7, July 2008, Pages 1615–1622