کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1519026 | 1511627 | 2006 | 5 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Study of insulator to metal transition in Rb4C60 by coherent and incoherent X-ray scattering under pressure
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موضوعات مرتبط
مهندسی و علوم پایه
مهندسی مواد
مواد الکترونیکی، نوری و مغناطیسی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
The equation of state (EOS) of Rb4C60 is determined by high-pressure X-ray diffraction measurements. We observe an abrupt jump in the compressibility of Rb4C60 between 0.5 and 0.8Â GPa which is attributed to a structural phase transition preserving the tetragonal symmetry. Pressure effects on electronic density are studied by measuring Compton profiles below and above the transition. The ab initio calculation of the electronic structure is used to obtain theoretical equation of state, which agrees well with the experimental results. The calculations are used to quantitatively identify different contributions to the Compton profiles. In particular, we point out an unexpected contraction of the C60 molecular volume under pressure which brings about significant effects on the electronic density of Rb4C60 compound.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Physics and Chemistry of Solids - Volume 67, Issues 5â6, MayâJune 2006, Pages 1132-1136
Journal: Journal of Physics and Chemistry of Solids - Volume 67, Issues 5â6, MayâJune 2006, Pages 1132-1136
نویسندگان
A.A. Sabouri-Dodaran, Ch. Bellin, M. Marangolo, F. Mauri, G. Fiquet, G. Loupias, M. Mezouar, Th. Buslaps, C. Hérold, F. Rachdi, S. Rabii,