کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1520680 | 1511790 | 2016 | 7 صفحه PDF | دانلود رایگان |

• We studied a magnetic transition of a natural goethite sample.
• It was observed by ESR the spin flop effect and the transition to the PM state.
• Spectra simulations showed ESR lines of different spins interactions with vicinity.
• TN was determined as 372 and 370 K by ESR and Magnetometry respectively.
A natural sample of the mineral goethite was characterized by X-band Electron Spin Resonance (ESR), vibrating sample Magnetometry and Mössbauer spectroscopy techniques, with the main objective of studying the magnetic transition from the antiferromagnetic to the paramagnetic state that this mineral undergoes upon reaching a certain critical temperature (Néel temperature). Although an ESR signal was not expected in goethite samples at room temperature, due to its antiferromagnetic arrangement, a resonance line was observed. This behavior was attributed to the existence of vacancies in the mineral structure. Increasing the temperature from RT to 352 K no significant change occurred in the ESR spectra. From 352 K, the goethite spectrum showed an additional ESR line, the intensity of this line grew until it stabilized at around 444 K. The appearance of this new resonance line, and its evolution with temperature, was attributed to two subsequent effects: firstly the spin flop effect from 352 to 372 K; and secondly, the transition to the paramagnetic state at TN = 372 K. Magnetometry and Mössbauer measurements corroborated this assumption and the transition temperature was identified by magnetometry as TN = 370 K. Simulations of the goethite ESR spectra in both antiferromagnetic and paramagnetic states were performed by deconvolution of the resonance lines into two contributions, one from species with vacancies in their vicinity, and another with complete vicinity.
Journal: Materials Chemistry and Physics - Volume 173, 15 April 2016, Pages 179–185