کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1522494 995311 2013 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Fabrication of Cu2S cathode for Li-ion battery via a low temperature dry thermal sulfuration method
موضوعات مرتبط
مهندسی و علوم پایه مهندسی مواد مواد الکترونیکی، نوری و مغناطیسی
پیش نمایش صفحه اول مقاله
Fabrication of Cu2S cathode for Li-ion battery via a low temperature dry thermal sulfuration method
چکیده انگلیسی
Cu2S film that directly grows on porous Cu foam has been fabricated by a novel dry thermal sulfuration approach. The crystalline structure and morphological observation of the as-synthesized Cu2S/Cu were characterized by X-Ray diffraction (XRD) and field-emission scanning electron microscopy (FE-SEM), respectively. The electrochemical performance of the Cu2S/Cu as cathode for Li-ion battery was studied by charge/discharge test and cyclic voltammetry (CV) measurement. The results indicate that the Cu2S/Cu cathode exhibits excellent cycle stability and rate capability. When applying a charge/discharge rate of 0.25 C, it delivers initial discharge and charge capacity of 0.74 and 0.40 mAh cm−2, respectively. After 100 cycles, the discharge and charge capacity are both 0.41 mAh cm−2, showing no obvious capacity attenuation. Besides, even after 140 cycles at various rates from 0.3 C to 60 C, the discharge capacity of the Cu2S/Cu cathode can restore 97.8% when lowering the charge/discharge rate to 0.3 C.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Materials Chemistry and Physics - Volume 143, Issue 1, 16 December 2013, Pages 349-354
نویسندگان
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